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Table of Contents

Energy Conservation Manual

Distillation Column Operations

Title

Disclaimer

Table of Contents

Abstract

List of Tables

List of Figures

Section 1 - Introduction 1 - 1

Section 2 - Design review, audit of energy and material balance 2 - 1

A. Review of plant design 2 - 1

B. Audit of actual plant operation 2 - 1

C. Data collection during plant operation 2 - 3

Section 3 - Energy saving improvements with minimal capital investements 3 - 1

A. Operating procedure revisions

(1) Reducing the reflux ratio of columns 3 - 1

(2) Lowering product specifications 3 - 3

(3) Lowering pumping costs 3 - 4

(4) Lowering steam usage 3 - 9

(5) Process heaters 3 -11

B. Scheduling shutdowns to maximize energy recovery and profits 3 -13

Section 4 - Energy savingins improvements with capital investements 4 - 1

A. Optimization of heat recovery - heat exchangers 4 - 1

B. Column revisions 4 - 5

(l) Additional or more Efficient trays 4 - 5

(2) Additional column draw 4 - 7

C. Optimization of recovery and use of energy 4 - 7

(1) Introduction 4 - 7

(2) Column Heat Utilization 4 - 9

2.1 Bottoms product 4 -10

2.2 Distillate product 4 -11

2.3 Condenser duty 4 -11

2.4 Reboiler duty 4 -11

2.5 Feed preheating 4 -12

(3) Changing the column's temperature 4 -12

(4) Two-stage condensation 4 -12

(5) Waste heat boilers 4 -13

(6) Multiple effect heat cascading for distillation columns 4 -13

(7) Split tower 4 -15

(8) Interreboilers, intercondensers, and feed preheating 4 -19

(9) Feed preheating 4 -21

(10) Interreboiler 4 -21

(11) Intercoolers and feed precoolers 4 -21

(12) Circulating refluxes 4 -22

D. Use of vapor recompression and heat pumps for distillation 4 -24

(1) Introduction 4 -24

(2) Distillation column's reflux and heat balance 4 -25

(3) Vapor recompression 4 -26

(4) Heat pump 4 -27

(5) Theory behind vapor-recompression and heat pumps 4 -28

5.1 The Carnot cycle 4 -28

5.2 The refrigeration cycle 4 -33

(6) Vapor recompression 4 -37

6.1 Situations 4 -37

6.2 Auxiliary heat transfer equipment 4 -38

6.3 Compressor drives and their energy costs 4 -40

6.4 Insulation of columns using vapor recompression or heat pumps 4 -41

6.5 Vapor recompression for interreboilers, other columns 4 -41

(7) Reasons for conversion of an existing column 4 -42

(8) Conversion of an existing column 4 -43

(9) Advantages of vapor recompression 4 -44

(10) Disadvantages of vapor recompression 4 -46

(11) Advantages and disadvantages of the heat pump 4 -49

(12) Guidelines for considering vapor recompression 4 -50

(13) Procedure for vapor recompression evaluation 4 -51

(14) Example, propane-propylene splitter 4 -54

14.1 Situation statement 4 -54

14.2 Solution 4 -55

(15) Work problem propane-propylene splitter with bottoms vapor recompression 4 -60

E. Improving control of distillation columns 4 -61

F. Reducing heat losses using insulation 4 -64

Section 5 - Economics 5 - 1

A. Definition of economic terms 5 - 2

(1) Profit 5 - 2

(2) Net back 5 - 2

(3) Depreciation 5 - 3

(4) Investment tax credit 5 - 5

(5) Fixed costs 5 - 5

(6) Variable costs 5 - 6

(7) Cash flow 5 - 6

(8) Discounted cash flow 5 - 6

(9) Return on investment (R.O.I.) 5 - 7

B. Concept of investment equivalence to save energy 5 - 8

C. Economic interpretations for energy savings 5 - 9

D. Steam economics 5 -11

E. Cooling water 5 -13

F. Compressed air 5 -14

G. Vacuum pumps and steam ejectors 5 -14

H. Exchangers used for heat recovery 5 -15

I. Conclusion 5 -15

Section 6 - Bibliography with abstracts 6 - 1

Section 7 - Appendices 7 - 1

A. Energy savings checklist - General 7 - 1

B. Process energy checklist 7 - 6

C. References - Technical articles 7 -10

D. Solution to work problem 4-F-15 7 -14

This page updated 29 August 2001.
© 2001 Andrew W. Sloley. All rights reserved.